Environmental Engineering
M. Mambwe; K.K. Kalebaila; T. Johnson
Abstract
BACKGROUND AND OBJECTIVES: With technological advances, mining industries use more crude oil and its products. Finding fast, effective, and eco-friendly repair techniques for oil-contaminated soil is crucial. Clay–titanium dioxide/manganese was used to investigate how oil breaks down in soil under ...
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BACKGROUND AND OBJECTIVES: With technological advances, mining industries use more crude oil and its products. Finding fast, effective, and eco-friendly repair techniques for oil-contaminated soil is crucial. Clay–titanium dioxide/manganese was used to investigate how oil breaks down in soil under sunlight. Various soil remediation techniques have been used to discard oil pollutants in soil. A polluted site must be cleaned effectively with a suitable method. Natural attenuation takes too long to produce positive results, whereas landfarming can produce toxic intermediates due to the organisms’ inability to degrade other oil components. Photochemical oxidation is a promising eco-friendly technique that can be employed as an alternative remediation method. The speed at which natural attenuation, photochemical oxidation, and landfarming could remove oil from contaminated soils was examined. Photochemical oxidation’s superiority as a remediation technique over landfarming is hypothesized.METHODS: Using clay modified with titanium dioxide and manganese, the effectiveness of landfarming and photochemical oxidation on oil-contaminated soil was investigated, together with the processes’ kinetics. To establish the processes’ effectiveness and kinetics, the oil residue was calculated at 7-day intervals for 35 days.FINDINGS: Initial oil concentration was 56.6 milligrams per kilogram, and degradation rates ranged from 23.91-80.47 percent. Highest oil reduction was 10.86 milligrams per kilogram. Combined remediation (biocarb and grafted clays) produced high degradation rate constants, k (0.046-0.049/day) and low degradation half-lives, t½ (15.2, 17.4 days). Photochemical oxidation rate constants ranged from 0.015-0.03984/day and half-lives ranged from 17.395-44.971 days, whereas landfarming had a rate constant of 0.008 and half-life of 83.094. Natural attenuation had the lowest k (0.007) and longest half-life (t½) of 94.8 days. Significant differences in means were observed among treatments (control, biocarb, and bicarb + grafted clays) at p ≤ 0.05, suggesting that treatment caused oil decrease in microcosms for biocarb + grafted clays. Grafted clays plus biocarb show potential for combined remediation of oil-contaminated soil.CONCLUSION: One primary indicator used to assess treatments’ efficacy is oil reduction, calculated using difference in oil content in soil before and after remediation. This shows that oil can be quickly removed from oil-contaminated soil by using biocarb + grafted South Luangwa with 80 percent oil reduction. Results suggest that photochemical oxidation may be used to effectively degrade oil and shorten remediation time. Photochemical oxidation is environmentally friendly and degrades oil faster than landfarming. Zambia’s Mopani Copper Mines can consider adopting photochemical oxidation as a remediation technique in treating oil-contaminated soil.
Environmental Engineering
L. Sulistyowati; N. Andareswari; F. Afrianto; A. Rais; M.F. Hafa; D. Darwiyati; A.L. Ginting
Abstract
BACKGROUND AND OBJECTIVES: The monitoring of the Brantas watershed showed a light-polluted status. This study began by identifying the priority of regional problems using importance-performance analysis. Furthermore, a hydrological analysis was conducted to determine the pollutant area of the Brantas ...
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BACKGROUND AND OBJECTIVES: The monitoring of the Brantas watershed showed a light-polluted status. This study began by identifying the priority of regional problems using importance-performance analysis. Furthermore, a hydrological analysis was conducted to determine the pollutant area of the Brantas watershed by applying terrain analysis. When terrain analysis in hydrology is combined with participatory community information, it can provide valuable insights into water pollution and help prioritize remediation efforts. Integrating local knowledge with scientific data can improve decision-making and increase the effectiveness of water management strategies.METHODS: The methodological approach employed in this study included importance-performance analysis to determine priority problems in Batu City and terrain analysis as a hydrological analysis to determine the pollutant area in the Brantas watershed. The importance-performance analysis assessment data were obtained from 197 respondents representing the occupations of the people of Batu City. The terrain analysis data were derived from the surface elevation data in the form of a digital elevation model.FINDINGS: According to the importance-performance analysis community assessment, urban trash management was one of the crucial yet low-rated features. The terrain analysis results demonstrated that business and industrial activities were distributed in locations with high flow accumulation values, indicating that the water pollution in Batu City was triggered by the presence of business and industrial activities in the watershed accumulation areas. Along the upstream Brantas watershed, 460 business and industrial activities were discovered. Therefore, the results of importance-performance analysis and terrain analysis had a correlation. They were also closely related to the assessment results of the contaminated Brantas watershed.CONCLUSION: The following are some recommendations for the watershed's quality improvement: 1) cooperation among the Government, communities, and the private sector for addressing water pollution issues; 2) the development of environmentally friendly technologies in water treatment; and 3) education and outreach to communities about the importance of preserving water resources. As a city experiencing rapid urban development, environmental degradation constitutes a risk to be borne. Accordingly, Batu City must continue to develop good environmental management for the sake of nature conservation because the urban system is a unit formed by the social economy and ecological environment subsystem.
