S. Rashad; A.S. El-Hassanin; S.S.M. Mostafa; G.A. El-Chaghaby
Abstract
Olive milling wastewater is a major problem facing the Mediterranean countries producing olive oil like Egypt. In the present study, olive milling wastewater rich with organic phenolic compounds, macro and micro nutrients was used as growing media for cyanobacteria. The cyanobacteria were grown on wastewater ...
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Olive milling wastewater is a major problem facing the Mediterranean countries producing olive oil like Egypt. In the present study, olive milling wastewater rich with organic phenolic compounds, macro and micro nutrients was used as growing media for cyanobacteria. The cyanobacteria were grown on wastewater to obtain two biofertilizers, one bioformulated from single culture of Spirulina platensis and the second from mixed culture of S. platensis, N. muscorum and A.oryzae. The produced biofertilizers, were applied on a sandy soil to grow celery plant under different levels (25, 50 and 75%) of the recommended chemical fertilizers, while the control did not receive any fertilizers in a greenhouse experiment at Giza Research station, Agricultural Research Center, Egypt during the summer season of 2018. Results indicated that application of biofertilizers led to a significant (p<0.05) increase in the height of plant, root and stem lengths over the control group. The number of leaves per plant as well as chlorophyll content were highest in the treatments of Bio-Mix 25 and 50%. Also, these treatments increased the total macro- and micro-nutrients of celery. There was very remarkable enhancement in some recorded sandy soil properties after harvest i.e., pH, total organic matter, total nitrogen, phosphorus and potassium by the treatments of Bio-Mix with 25 and 50%. The present study concluded that 1/4 or 1/2 of the recommended dose of NPK fertilizers could be saved for celery growth by using Bio-Mix product from cyanobacteria and olive milling wastewater as a promising eco-friendly bio-organic fertilizer.
Sh.F. Abd El-Kader; G.A. El-Chaghaby; G.M. Khalafalla; R.I. Refae; H.M. Elshishtawy
Abstract
Congo red is a synthetic azo-dye dye with many industrial applications. The effluents containing azo dyes are causing several environmental hazards and thus should be treated prior to their discharge. The present work investigates the possible use of a novel microbial consortium from sheep compost for ...
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Congo red is a synthetic azo-dye dye with many industrial applications. The effluents containing azo dyes are causing several environmental hazards and thus should be treated prior to their discharge. The present work investigates the possible use of a novel microbial consortium from sheep compost for the decolorization of Congo red dye. The effect of different parameters including contact time, dye concentration and inoculum concentration on dye decolorization were investigated. The kinetic of dye decolorization was also assessed and the biodegradation of the dye was confirmed by different techniques. The results showed that the microbial consortium decolorized about 98% of Congo red (500 mg/L) after 24h. The efficiency of the decolorization decreased from 95% to 62% when the dye concentration increased from 100 to 500mg/L. Also, it was noticed that 75% of Congo red (25 mg/L) was decolorized at an inoculum rate of 2.5%. The kinetic results suggested that the decolorization of Congo red by the studied consortium follows the first order kinetic model. Also the maximum substrate consumption rate (Vmax) according to Michaelis- Menten model was found to be 19.30 mg/h/L and the decolorization rate constant (Km) was 116.93 mg/L. The biodegradation of Congo red was further confirmed by HPLC and GC-Ms analysis which revealed the presence of some spectral differences between the untreated dye sample and the treated one. In conclusion, the results of the present work suggest that microbial consortium from sheep compost could have potential application for bioremediation of industrial effluents containing Congo red dye.
Environmental Science
N.T. Abdel-Ghani; G.A. El-Chaghaby; F.S. Helal
Abstract
In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric ...
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In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. The phenol adsorption capacity of the prepared carbons was evaluated. The different factors affecting phenol’s removal were studied including: contact time, solution pH and initial phenol concentration. The optimum phenol removal was obtained after a contact time of 300 min. and at an initial phenol solution pH 7. The maximum removal percentages were determined at 5mg/l initial phenol concentration as 79, 93, 94 and 98% for AC0, AC1, AC2 and AC3; respectively. The adsorption of phenol on African beech sawdust activated carbons was found to follow the Lagergren first order kinetics and the intraparticle diffusion mechanism gave a good fit to the experimental data. The isothermal models applied fitted the experimental data in the order: Langmuir> Dubinin–Radushkevich> Freundlich and Temkin.
Environmental Science
N.T. Abdel-Ghani; E.S.A. Rawash; G.A. El-Chaghaby
Abstract
The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m²/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated ...
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The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m²/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated carbon was 120min. The adsorption data was modeled by equilibrium and kinetic models. The pseudo- first and second order as well as the Elovichkinetic models were applied to fit the experimental data and the intraparticle diffusion model was assessed for describing the mechanism of adsorption. The data were found to be best fitted to the pseudo-second order model with a correlation coefficient (R2=0.986). The intraparticle diffusion mechanism also showed a good fit to the experimental data, showing two distinct linear parts assuming that more than one step could be involved in the adsorption of nitrophenol by the activated carbon. The equilibrium study was performed using three models including Langmuir, Freundlich and Temkin. The results revealed that the Temkin equilibrium model is the best model fitting the experimental data (R2=0.944). The results of the present study proved the efficiency of using olive cake based activated carbon as a novel adsorbent for the removal of nitrophenol from aqueous solution.