Environmental Science
N.T. Abdel-Ghani; G.A. El-Chaghaby; F.S. Helal
Abstract
In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric ...
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In the present study, different activated carbons were prepared from carbonized African beech wood sawdust by potassium hydroxide activation. The activated carbons were characterized by brunauer–emmett–teller, scanning electron microscope, fourier transform infrared spectroscopy, and thermogravimetric analyzer. The phenol adsorption capacity of the prepared carbons was evaluated. The different factors affecting phenol’s removal were studied including: contact time, solution pH and initial phenol concentration. The optimum phenol removal was obtained after a contact time of 300 min. and at an initial phenol solution pH 7. The maximum removal percentages were determined at 5mg/l initial phenol concentration as 79, 93, 94 and 98% for AC0, AC1, AC2 and AC3; respectively. The adsorption of phenol on African beech sawdust activated carbons was found to follow the Lagergren first order kinetics and the intraparticle diffusion mechanism gave a good fit to the experimental data. The isothermal models applied fitted the experimental data in the order: Langmuir> Dubinin–Radushkevich> Freundlich and Temkin.
Environmental Science
N.T. Abdel-Ghani; E.S.A. Rawash; G.A. El-Chaghaby
Abstract
The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m²/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated ...
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The present work was carried out to evaluate the removal of p-nitrophenol by adsorption onto olive cake based activated carbon having a BET surface area of 672 m²/g. The batch adsorption experimental results indicated that the equilibrium time for nitrophenol adsorption by olive cake-based activated carbon was 120min. The adsorption data was modeled by equilibrium and kinetic models. The pseudo- first and second order as well as the Elovichkinetic models were applied to fit the experimental data and the intraparticle diffusion model was assessed for describing the mechanism of adsorption. The data were found to be best fitted to the pseudo-second order model with a correlation coefficient (R2=0.986). The intraparticle diffusion mechanism also showed a good fit to the experimental data, showing two distinct linear parts assuming that more than one step could be involved in the adsorption of nitrophenol by the activated carbon. The equilibrium study was performed using three models including Langmuir, Freundlich and Temkin. The results revealed that the Temkin equilibrium model is the best model fitting the experimental data (R2=0.944). The results of the present study proved the efficiency of using olive cake based activated carbon as a novel adsorbent for the removal of nitrophenol from aqueous solution.
